Isotopes of Carbon







Isotopes of Carbon





Isotopes of carbon

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Carbon (C)
Standard atomic mass: 12.0107(8) u

Contents

Natural isotopes

There are 3 naturally occurring isotopes of carbon: 12, 13 & 14.

Table

nuclide
symbol
Z(p) N(n)  
isotopic mass (u)
 
half-life nuclear
spin
representative
isotopic
composition
(mole fraction)
range of natural
variation
(mole fraction)
excitation energy
8C 6 2 8.037675(25) 2.0(4) x 10-21 s [230(50) keV] 0+
9C 6 3 9.0310367(23) 126.5(9) ms (3/2-)
10C 6 4 10.0168532(4) 19.290(12) s 0+
11C 6 5 11.0114336(10) 20.334(24) min 3/2-
12C 6 6 12 by definition Stable 0+ 0.9893(8) 0.98853-0.99037
13C 6 7 13.0033548378(10) Stable 1/2- 0.0107(8) 0.00963-0.01147
14C 6 8 14.003241989(4) 5.70(3) x 103 years 0+ <10-12
15C 6 9 15.0105993(9) 2.449(5) s 1/2+
16C 6 10 16.014701(4) 0.747(8) s 0+
17C 6 11 17.022586(19) 193(5) ms (3/2+)
18C 6 12 18.02676(3) 92(2) ms 0+
19C 6 13 19.03481(11) 46.2(23) ms (1/2+)
20C 6 14 20.04032(26) 16(3) ms [14(+6-5) ms] 0+
21C 6 15 21.04934(54)# <30 ns (1/2+)#
22C 6 16 22.05720(97)# 6.2(13) ms [6.1(+14-12) ms] 0+

Notes

  • The precision of the isotope abundances and atomic mass is limited through variations. The given ranges should be applicable to any normal terrestrial material.
  • Values marked # are not purely derived from experimental data, but at least partly from systematic trends. Spins with weak assignment arguments are enclosed in parentheses.
  • Uncertainties are given in concise form in parentheses after the corresponding last digits. Uncertainty values denote one standard deviation, except isotopic composition and standard atomic mass from IUPAC which use expanded uncertainties.
  • 12C is of particular importance as it is used as the standard from which atomic masses of all nuclides are measured: its atomic mass is by definition 12.

Paleo-climate

12C and 13C can be used as temperature tracers that explain ocean circulation. Plants find it easier to use the lighter isotopes (12C) when they convert sunlight and carbon dioxide into food , thus large blooms of plankton (free-floating organisms) draw large amounts of 12C into the oceans. If those oceans are stratified layers of warm water near the top, and colder water deeper down) the water cannot circulate, thus when the plankton dies it sinks and carries 12C with them, making the surface layers relatively rich in 13C. Where the cold waters well up from the depths (North Atlantic) it carries the 12C with it. Thus, when the ocean was less stratified than today, there was plenty of 12C in the skeletons of surface-dwelling species. Other indicators of past climate include the presence of tropical species, coral growths rings, etc. (Flannery, 2005)

References


Isotopes of boron Isotopes of carbon Isotopes of nitrogen
Index to isotope pages · Table of nuclides

See also


Isotopes of Carbon


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